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Extra info for Inorganic Chemistry of the Transition Elements: v. 3: A Review of Chemical Literature (Specialist Periodical Reports)
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N. Latyaeva, L. I. Vishinskaya, and A. M. Rabinovitch, J . , 1973,49,441. K. H. Thiele, E. Kohler, and B. Adler, J . , 1973,50, 153. -Halides and Oxyhalides. A new X-ray structural determination of Li,ZrF, has resolved ambiguities in the position of the Li' ions. 87A remarkable versatility of structural units has been identified in the CU"-H,O-[Z~F,]~system. Crystals of CuZrF6,4H,0 involve infinite chains of - - [ZrF,l2- - - -[Cu(H,0),I2+ - -- distorted octahedral units. K,CuZrF6,2H,0 contains [Zr,Fl,]4- ions which are composed of two ZrF, pentagonal bipyramids sharing an equatorial edge.