Handbook of Battery Materials, Second Edition

A one-stop source for either researchers and improvement engineers, this complete guide serves as an everyday reference, changing lots of person papers.
This moment variation good points twenty percentage extra content material with new chapters on battery characterization, procedure know-how, failure mechanisms and approach improvement, plus up-to-date details on vintage batteries in addition to fullyyt new effects on complicated approaches.
The authors, from such prime associations because the US nationwide Labs and from businesses resembling Panasonic and Sanyo, current a balanced view on battery examine and large-scale purposes. They stick to a enormously materials-oriented course in the course of the whole box of battery study, therefore permitting readers to quick locate the data at the specific fabrics procedure appropriate to their study.

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Extra info for Handbook of Battery Materials, Second Edition

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For many other applications such as notebooks, MP3-players, cellular phones, or starter batteries in cars only rechargeable battery systems, for example, lithium-ion batteries or lead–acid batteries, can be considered from the point of view of cost and the environment. The wide variety of applications has led to an immense number of configurations and sizes, for example, small round cells for hearing aids or large prismatic cells like lead–acid batteries for use in trucks. Here the great variety of demands has the consequence that nowadays no battery system is able to cope with all of them.

The product of the temperature and the entropy describes the reversible amount of heat consumed or released during the reaction. With tabular values for the enthalpy and the entropy it is possible to obtain G. Using the reaction free energy, G, the cell voltage ε0 can be calculated. First, the number n of exchanged moles of electrons during an electrode reaction must be determined from the cell reaction. For the Daniell element (see example below), 2 mol of electrons are released or received, respectively.

4 expresses the fact that 1 mol electrons discharges • 1 mol monovalent ions, • 1/2 mol bivalent ions, or • 1/z mol z-valent ions. 4 Charging The charging process can only be applied to secondary cells, because, in contrast to primary cells, the electrochemical reactions are reversible. If primary cells are charged, this may lead to electrochemical side reactions, for example, the decomposition of the electrolyte solution with dangerous follow-up reactions leading to explosions [8]. While charging, ions are generally reduced at the negative electrode and an oxidation process takes place at the positive electrode.

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