Dendrimers III: Design, Dimension, Function by Uwe-Martin Wiesler, Tanja Weil, Klaus Müllen (auth.), Prof.

By Uwe-Martin Wiesler, Tanja Weil, Klaus Müllen (auth.), Prof. Dr. Fritz Vögtle (eds.)

Following the 1st volumes "Dendrimers" (TCC vol. 197) and "Dendrimers II" (TCC vol. 210), the 3rd quantity facing this subject is now showing in print (the "tetralogy" on dendrimers will quickly be accomplished with the fourth volume). the current quantity includes a set of up to date experiences written by way of well known pioneers of study within the dendrimer box, 3 of whom lectured on the 1. overseas Dendrimer Symposium (IDS-1 1999) in Frankfurt. a spotlight of this quantity is the range of fabric houses of soppy and shape-persistent dendrimers. As its predecessors did, this quantity breaks during the frontiers to neighboring disciplines and, in an interdisciplinary procedure, addresses issues resembling polydisperse, hyperbranched macromolecules (dendritic polymers), the research of form and density through small-angle scattering suggestions, finely dispersed metals (dendrimers as catalysts), and nanotechnology just about strength applications.

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4 Water Soluble Resins . . . . . . . . . . . . . Poly(ethyleneoxide) Functional Hyperbranched Polyesteramides Fluoroalkyl Functional Hyperbranched Polyesteramides . . Multifunctional Hyperbranched Polyesteramides . . . . 7 Conclusions 8 References . . . . 70 70 75 78 . . . . . . . . . . . . . . . . 78 . . . . . . . . . . . . . . . . 79 List of Abbreviations DIPA GA HHPA OSA PA SA THPA diisopropanolamine glutaric anhydride cis-1,2-cyclohexane-dicarboxylic anhydride 1-oct-2-ene-succinic anhydride phthalic anhydride succinic anhydride cis-1,2-cyclohex-4-ene-dicarboxylic anhydride 1 Introduction The attractiveness of dendritic molecules follows from their unique structure like the large number of end groups, enabling multi-functionality on the same molecule, special rheological behavior and cavities due to the spherical structure.

Furthermore, financial support by the Bundesministerium für Bildung and Forschung (03C0299 7) and the Volkswagen Stiftung are gratefully acknowledged. -M. W. also thanks the Fonds der Chemischen Industrie and the Bundesministerium für Bildung und Forschung for a Ph. D. grant. Last, but not least, we thank all the people who aided us in the preparation of this review. We would like to commend Dr. M. Watson who has kindly read the manuscript and made many valuable comments. J. A. Harbison, A. Herrmann, D.

Thus the concept of the synthesis allows a broad variety of structures and the resulting properties like polarity or viscosity can be adjusted and fine-tuned for a broad number of applications. This enables the hyperbranched polyesteramides to be used in a variety of (potential) applications, such as crosslinkers in coatings, as toner resin, for dyeing polyolefins, as surfactants, or in cosmetics. Especially impressive is the disperse dyeing of polypropylene fibers, which has been a problem for decades.

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