Comprehensive Coordination Chemistry Synthesis Reactions: by Sir. G. Wilkinson

By Sir. G. Wilkinson

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Wohler and A. Berthmann, Ber. Deursch. Chem. Ges.. 1929, 62, 2748. W. Beck and K. Feldl, 2. Anorg. AIIg. , 1965, 341, 113. B. Klatt and K. Schwabe, J. EIectroanal. , 1970, 24, 61. 2 Silicon, Germanium, Tin and Lead PHILIP G. 1 SILICON,GERMANIUM, TIN AND LEAD SPECIFS AS LIGANDS Complexes of transition metals in which a Group IV metal moiety functions as a donor ligand are quite profuse. Many routes for their synthesis are available, and many types of structure are adopted. The formally tetravalent organometallic M'" R,X,_, (R = organic group, X = halogen; x = 1-3) ligand units function formally as single electron donors, whilst bivalent species M11X2 (X = unidentate or bidentate group) are formally analogous to other more common two-electron donor molecules such as phosphines and arsines.

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